Palladium catalysts for dehydrogenation of ammonia borane with preferential B-H activation.
نویسندگان
چکیده
Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H(2) in less than 60 s at 25 degrees C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.
منابع مشابه
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عنوان ژورنال:
- Journal of the American Chemical Society
دوره 132 29 شماره
صفحات -
تاریخ انتشار 2010